Benthic nutrient fluxes along the Laurentian Channel: Impacts on the N budget of the St. Lawrence marine system     

Benoît Thibodeau  Moritz F. Lehmann  Jacqueline Kowarzyk  Alfonso Mucci  Yves Gélinas  Denis Gilbert  Roxane Maranger  Mohammad Alkhatib 《Estuarine, Coastal and Shelf Science》2010

Water column concentrations and benthic fluxes of dissolved inorganic nitrogen (DIN) and oxygen (DO) were measured in the Gulf of St. Lawrence and the Upper and Lower St. Lawrence Estuary (USLE and LSLE, respectively) to assess the nitrogen (N) budget in the St. Lawrence (SL) system, as well as to elucidate the impact of bottom water hypoxia on fixed-N removal in the LSLE. A severe nitrate deficit, with respect to ambient phosphate concentrations (N*∼−10 μmol L⁻¹), was observed within and in the vicinity of the hypoxic bottom water of the LSLE. Given that DO concentrations in the water column have remained above 50 μmol L⁻¹, nitrate reduction in suboxic sediments, rather than in the water column, is most likely responsible for the removal of fixed N from the SL system. Net nitrate fluxes into the sediments, derived from pore water nitrate concentration gradients, ranged from 190 μmol m⁻² d⁻¹ in the hypoxic western LSLE to 100 μmol m⁻² d⁻¹ in the Gulf. The average total benthic nitrate reduction rate for the Laurentian Channel (LC) is on the order of 690 μmol m⁻² d⁻¹, with coupled nitrification-nitrate reduction accounting for more than 70%. Using average nitrate reduction rates derived from the observed water column nitrate deficit, the annual fixed-N elimination within the three main channels of the Gulf of St. Lawrence and LSLE was estimated at 411 × 10⁶ t N, yielding an almost balanced N budget for the SL marine system.  相似文献   

Methane-derived authigenic carbonates from active hydrocarbon seeps of the St. Lawrence Estuary,Canada     

Denis Lavoie  Nicolas Pinet  Mathieu Duchesne  Andrée Bolduc  Richard Larocque 《Marine and Petroleum Geology》2010

Nearly 2000 pockmarks with diameters ranging from a few tens of meters up to 700 m are present on the seafloor of the St. Lawrence Estuary in eastern Canada. Coring of some pockmarks resulted in the recovery of various-sized and shaped carbonate concretions in a predominantly silty mud matrix. Petrographic and geochemical data on four authigenic carbonate concretions are reported as well as data from shell material in the unconsolidated sediment. Video observations and echo-sounder images indicate that the sampled pockmarks are actively gas venting. The video images show significant look-alike microbial mats in areas where gas is venting. The carbonate concretions are primarily made up of carbonate cements with varying percentage of shell fragments, micrite particles and fine-grained clastics. Orthorhombic crystal morphology and diagenetic fabrics including isopachous layers and botryoids characterize the aragonite cement. Oxygen isotopes ratios for the cement crusts do not record any thermal anomaly at the site of precipitation with δ¹⁸O_VPDB ratios (+3‰) in equilibrium with cold (5 °C) deep marine waters, whereas significant negative δ¹³C_VPDB ratios (−9.9 to −33.5‰) for cement and shell material within concretions indicate that the carbonates largely derive from the microbial oxidation of methane. The δ¹³C_VPDB ratios of aragonite shells (−2.7 to −5.6‰) taken from unconsolidated sediments at some distance from the concretions/vents show variable dilution of HCO₃⁻ with negative δ¹³C_VPDB ratios derived from microbial oxidation of methane with isotopically normal (0‰) marine bicarbonate. These results are in agreement with other lines of evidence suggesting that pockmarks formed through the recent and still active release of gas from a reservoir within the Paleozoic sedimentary succession.  相似文献   

Joint editorial – Fostering innovation and improving impact assessment for journal publications in hydrology     

Demetris Koutsoyiannis  Günter Blöschl  András Bárdossy  Christophe Cudennec  Denis Hughes  Alberto Montanari 《水文科学杂志》2013,58(7):1170-1173

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The Congo Basin forests in a changing climate: Policy discourses on adaptation and mitigation (REDD+)     

Olufunso A. Somorin  H. Carolyn Peach Brown  Ingrid J. Visseren-Hamakers  Denis J. Sonwa  Bas Arts  Johnson Nkem 《Global Environmental Change》2012,22(1):288-298

This paper discusses the discourses on climate change adaptation and mitigation that are currently at the forefront in the Congo Basin. On mitigation, the forests have enormous opportunities to contribute to the reducing emissions from deforestation and forest degradation (REDD+) mechanism. But the forest itself and its multiple dependent societies and sectors need to adapt to potential climate risks. Hence, actors are debating the design of climate change policy in the forest sector. Theoretically, we combine the agency-focus of frame analysis and discourse theory to analyze how different agents hold frames on climate change adaptation and mitigation policies in the region. This paper draws upon interviews with 103 different actors from government, international organizations, non-governmental organizations, research institutions and private sector in three countries: Cameroon, Central African Republic (CAR) and Democratic Republic of Congo (DRC). Three discourses were found on policy response to climate change in the forest sector: mitigation policy only, separated policy on adaptation and mitigation, and an integrated policy on adaptation and mitigation. The various frames articulated around each discourse by the coalitions include elements of: costs and benefits, scale of operation, effectiveness, financial resources and implementation mechanisms. Overall, the mitigation discourse, through its mix of actors, resources and interests seems to be stronger than the adaptation discourse. The paper finally outlines a number of implications of the discourses for policy design.  相似文献   

Mechanisms of seismic quiescences   总被引：7，自引：0，他引：7  

Christopher H. Scholz 《Pure and Applied Geophysics》1988,126(2-4):701-718

In the past decade there have been major advances in understanding the seismic cycle in terms of the recognition of characteristic patterns of seismicity over the entire tectonic loading cycle. The most distinctive types of patterns are seismic quiescences, of which three types can be recognized:post-seismic quiescence, which occurs in the region of the rupture zone of an earthquake and persists for a substantial fraction of the recurrence time following the earthquake,intermediate-term quiescences, which appear over a similar region and persist for several years prior to large plate-rupturing earthquakes, andshort-term quiescences, which are pronounced lulls in premonitory swarms that occur in the hypocentral region hours or days before an earthquake. Although the frequency with which intermediate-term and short-term quiescences precede earthquakes is not known, and the statistical significance of some of the former has been challenged, there is a need, if this phenomena is to be considered a possibly real precursor, to consider physical mechanisms that may be responsible for them.The characteristic features of these quiescences are reviewed, and possible mechanisms for their cause are discussed. Post-seismic quiescence can be readily explained by any simple model of the tectonic loading cycle as due to the regional effect of the stress-drop of the previous principal earthquake. The other types of quiescence require significant modification to any such simple model. Of the possibilities considered, only two seem viable in predicting the observed phenomena, dilatancy hardening and slip weakening. Intermediate-term quiescences typically occur over a region equal to or several times the size of the rupture zone of the later earthquake and exhibit a relationship between the quiescence duration and size of the earthquake: they thus involve regional hardening or stress relaxation and agree with the predictions of the dilatancy-diffusion theory. Short-term quiescences, on the other hand, are more likely explained by fault zone dilatancy hardening and/or slip weakening within a small nucleation zone. Because seismicity is a locally relaxing process, seismicity should follow a behaviour known in rock mechanics as the Kaiser effect, in which only a very slight increase in strength, due to dilatancy hardening or decrease in stress due to slip weakening, is required to cause quiescence. This is in contrast to other precursory phenomena predicted by dilatancy, which require large dilatant strains and complete dilatancy hardening.Lamont-Doherty Geological Observatory  相似文献   

Simplified dynamic and static Green's functions in transversely isotropic media     

Wenjie Dong  Denis P. Schmitt 《Geophysical Journal International》1994,119(1):231-242

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Urban and regional problems—British and Soviet perspectives     

Denis J.B. Shaw 《Geoforum》1990,21(4)

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Multivariable variogram and its application to the linear model of coregionalization   总被引：1，自引：0，他引：1  

Gilles Bourgault  Denis Marcotte 《Mathematical Geology》1991,23(7):899-928

In this article, we present the multivariable variogram, which is defined in a way similar to that of the traditional variogram, by the expected value of a distance, squared, in a space withp dimensions. Combined with the linear model of coregionalization, this tool provides a way for finding the elementary variograms that characterize the different spatial scales contained in a set of data withp variables. In the case in which the number of elementary components is less than or equal to the number of variables, it is possible, by means of nonlinear regression of variograms and cross-variograms, to estimate the coregionalization parameters directly in order to obtain the elementary variables themselves, either by cokriging or by direct matrix inversion. This new tool greatly simplifies the procedure proposed by Matheron (1982) and Wackernagel (1985). The search for the elementary variograms is carried out using only one variogram (multivariable), as opposed to thep(p + 1)/2 required by the Matheron approach. Direct estimation of the linear coregionalization model parameters involves the creation of semipositive definite coregionalization matrices of rank 1.  相似文献   

Copper Uptake by Blue-Green Algae     

V. Lüderitz  F. Scholz 《洁净——土壤、空气、水》1989,17(5):537-542

Experiments to study the influence of biomass concentration and pH on copper uptake by blue-green algae were performed. Differential pulse anodic stripping voltammetry (DPASV) was used for copper analysis. The maximum copper uptake per unit of biomass depends only on copper concentration and not on biomass concentration. Hence the copper toxicity is independent of biomass over a wide range. A main factor influencing copper uptake is the pH. Whereas the copper uptake of Aphanizomenon gracile is rapid at pH = 8.2 we did not find a significant uptake at pH = 5.7. The copper uptake at the higher pH value is followed by a nearly complete release of this copper, accompanied by a fast shortening of trichomes. There was no significant copper uptake in Oscillatoria redekei at pH = 8.2, but at pH = 7.2 the uptake pattern of this species is similar to that of Aphanizomenon at pH = 8.2. The results suggest that the metal ion uptake mechanisms of different species have not the same pH optima.  相似文献   

Generalized cross-validation for covariance model selection   总被引：4，自引：0，他引：4  

Denis Marcotte 《Mathematical Geology》1995,27(5):659-672

A weighted cross-validation technique known in the spline literature as generalized cross-validation (GCV), is proposed for covariance model selection and parameter estimation. Weights for prediction errors are selected to give more importance to a cluster of points than isolated points. Clustered points are estimated better by their neighbors and are more sensitive to model parameters. This rational weighting scheme also provides a simplifying significantly the computation of the cross-validation mean square error of prediction. With small- to medium-size datasets, GCV is performed in a global neighborhood. Optimization of usual isotropic models requires only a small number of matrix inversions. A small dataset and a simulation are used to compare performances of GCV to ordinary cross-validation (OCV) and least-squares filling (LS).  相似文献